Abstract
Redox data obtained from cyclic voltammetry experiments of the FeII/III and ring-based oxidation and reductions of subphthalocyanines containing a ferrocenylcarboxylic acid as axial ligand, is presented in this data in brief article. The FeII/III oxidation of ferrocenylsubphthalocyanines which containing the electron-withdrawing fluorine atoms at the peripheral and non-peripheral positions, are ca. 0.100 V more positive than FeII/III oxidation of ferrocenylsubphthalocyanines containing hydrogens at the peripheral and non-peripheral positions. For more insight into the reported data, see the related research article “Redox and photophysical properties of four subphthalocyanines containing ferrocenylcarboxylic acid as axial ligands” [1].
Highlights
Redox data obtained from cyclic voltammetry experiments of the FeII/III and ring-based oxidation and reductions of subphthalocyanines containing a ferrocenylcarboxylic acid as axial ligand, is presented in this data in brief article
Electrochemical studies by means of cyclic voltammetric (CV) experiments were performed in an MBraun Lab Master SP glove box under a high purity argon atmosphere (H2O and O2 < 10 ppm), utilizing a Princeton Applied Research PARSTAT 2273 potentiostat, running Powersuite software (Version 2.58)
Data for the formal reduction potential (E0’) of the internal standard DmFc (left peak, red dotted line), and of ferrocene oxidation of the axial ligand (marked as Fc), are indicated in V
Summary
Oxidation and reduction data of four subphthalocyanines with axially coordinated ferrocenylcarboxylic acids Redox data obtained from cyclic voltammetry experiments of the FeII/III and ring-based oxidation and reductions of subphthalocyanines containing a ferrocenylcarboxylic acid as axial ligand, is presented in this data in brief article. The FeII/III oxidation of ferrocenylsubphthalocyanines which containing the electron-withdrawing fluorine atoms at the peripheral and non-peripheral positions, are ca.
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