Abstract

Batch experiments were employed to examine the influence of oxalic acid on release kinetics of potassium (K) from soils along with adsorption and desorption of soil K+. The soils used were three rice soils from high-, mid-, and low-altitude zones. The results showed that soil K extracted using 0.2 mol L–1 oxalic acid was similar to that of 1 mol L–1 boiling nitric acid (HNO3). The relation between K release (y) and concentrations of oxalic acid (c) could be best described as y = a + b log c, whereas the best-fit kinetic equation of K release was y = a + b √t. The K release for soils was in the order Bonbagh > Ganasthan > Kreeri. An oxalic acid solution with low pH was able to release more K. Oxalic acid decreased soil K+ adsorption and increased desorption, the effect of which tended to be greater at lower pH.

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