Abstract

THE ABSORPTION SPECTRUM OF OXYGEN.—About three years ago M. Egorofif was able to show that the great groups A and B in the solar spectrum were due to the absorption of oxygen. More recently the a band was also found to be due to the same gas. M. Janssen, studying the absorption of oxygen has now discovered that under certain conditions the gas yields another spectrum, composed no longer of lines easily separated, but of shaded bands which can only be resolved with great difficulty. This system of bands appears for moderate pressures much later than the spectrum of lines, but it shows itself very quickly with increase of the density: the two systems are so different that it is possible to obtain either the first without the second or vice versâ. M. Janssen was at first unable to explain how it was that these bands were not visible in the solar spectrum when they were easily obtained by passing light through thicknesses of oxygen far less than the sun's light has to traverse before reaching us. But further experiments showed that these bands did not develop in proportion to the thickness of the stratum of oxygen producing them, multiplied by its density, but in proportion to the thickness multiplied by the square of the density. The density of our atmosphere being small as compared with some of the pressures at which M. Janssen worked, the non-appearance of these bands amongst the telluric lines of the solar spectrum is readily explained.

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