Abstract
Physical origins of the chemical (energy) shifting of Auger electron lines in the spectra of Al–Li, Ba (by 1.4 eV) and Mg–Ba (by 2 eV) systems containing cluster-forming alloying elements such as barium have been discussed. The observed peaks are associated with the formation of Al18Ba9 and Mg16Ba2 cluster compounds characterized by their own electron configurations.
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