Abstract

The study described in the present paper is focused on the N 2O–H 2 reaction on the Ir(1 1 0) surface and, in particular, on different kinds of oscillatory behaviour, including the route to chaos. Oscillations in rate were observed in the temperature range between 460 and 464 K, at a N 2O pressure of 1 × 10 −6 mbar with H 2/N 2O ratios close to 1. Upon minor changes in the H 2/N 2O ratio, a series of period doublings is observed, resulting finally in aperiodic behaviour.

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