Abstract
Mixtures of alkali metal chlorides used as electrolytes in pyrochemical processes for nuclear fuel production and spent nuclear fuel reprocessing were subjected to conversion into orthophosphate ceramic materials based on langbeinite mineral. The results of the solid-state synthesis of the phosphates are described. The phase and chemical composition, chemical stability, and heat resistance of the orthophosphates were studied by X-ray phase analysis, X-ray spectrum microanalysis, emission spectrum analysis, and scanning electron microscopy. Quantitative incorporation of alkali metal cations, including Cs, into such materials was proved. The use of a binder (89% Bi2O3 + 11% NaF mixture) considerably increases the density of the ceramic prepared and substantially enhances its chemical stability.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
