Abstract

AbstractRegioselective ortho difunctionalization of arenes is highly desirable yet challenging in organic synthesis. Here, we briefly discuss various methods for ortho difunctionalization of arenes and highlight a novel ortho-heterobimetallic arylene complex enabled by heterobimetallic synergism, which shows great potential in regioselective ortho difunctionalizations.1 Introduction2 Distinct Reactivity of C–Fe and C–Ti Bonds3 E/E′ ODFs by Fe/Ti-Heterobimetallic Intermediate4 Nu/E ODFs by Fe/Ti -Heterobimetallic Intermediate5 Summary and Outlook

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