Abstract

e-Fe2O3 phase is recognized as an attractive material, in both technological and scientific point of view, since it can achieve very high room-temperature coercivity (10–20 kOe). In this paper, multi-phase samples Fe2O3/SiO2 with slightly different $${\text{Fe/Si}}~$$ molar ratio were produced by sol–gel synthesis route. The obtained samples were characterized by various experimental techniques including XRD, TA, FTIR, and $${\text{SQUID}}$$ (DC and AC magnetic measurements). It was found that both samples consisted of α-Fe2O3 and e‑Fe2O3 phases embedded in the silica matrix, and showed very similar structural and magnetic properties, except that displayed significantly different room-temperature intrinsic coercivity field values: HciS1 = 14.3 kOe and HciS2 = 7.5 kOe. We have discussed possible origin of thus high intrinsic coercivity field variation.

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