Origin of the D line in the Raman spectrum of graphite: A study based on Raman frequencies and intensities of polycyclic aromatic hydrocarbon molecules

Abstract

A common valence force field for polycyclic aromatic hydrocarbons (PAHs) and graphite has been used in order to explain their Raman spectra from a unified viewpoint. On this basis the correlation observed between experimental spectra has been explained and rationalized. Quantum chemical density functional theory calculations of Raman intensities of small PAHs have been also performed, supporting the conclusions obtained from the dynamical analysis. The results obtained are useful for the characterization of materials containing graphitic domains and provide some new insight on the nature of the D peak in disordered graphite.