Abstract

Laser induced internal cooling has been investigated in a new fluorochloride glass (CNBZn) and a fluoride glass (BIG) doped with 2.1x10 20 Yb 3+ ions/cm 3 and in a Kpb 2 Cl 5 crystal doped with 5x10 19 Yb 3+ by using collinear photothermal deflection and conventional laser excitation spectroscopies under high photon irradiances. The cooling efficiency for CNBZn glass which is approximately 2% relative to the absorbed laser power at 1010 nm and 300 K falls about 20% at 77 K. The cooling efficiency for BIG glass was only approximately 6% at room temperature. For the Yb 3+ doped Kpb 2 Cl 5 crystal we have shown internal laser cooling with a cooling efficiency of about 0.2% at room temperature. This is the third ytterbium-doped crystal, after Kgd(WO 4 ) (Ref.10) and YAG (Ref.11), in which anti-Stokes laser-induced internal cooling has been demonstrated. The observed temperature dependence of the cooling process can be explained by a simple model accounting for the photon-ion- photon interaction.

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