Origin of high bromide concentration in the water sources in Jordan and in the Dead Sea water

Abstract

The Dead Sea is worldwide a major bromine provider for industry with an average concentration of 5.2 g/l of bromide compared to 0.065 mg/l in seawater and with a Cl/Br weight ratio in the Dead Sea water of about 42 compared to around 300 in oceanic water. The origin of the high bromide concentration in the Dead Sea has not yet been adequately clarified. In the course of this study, the bromide concentrations in the different surface and groundwater bodies in Jordan were analyzed and the types of rocks with which these waters were in contact were identified. Analyses carried out up to about 30 years ago and recent analyses confirm the natural origin of bromide in the water and also confirm that the analyzed sources are not polluted by anthropogenic bromide sources. It was found that a variety of these surface and groundwater sources contain high concentrations of bromide which discharges into the Dead Sea and contribute to its high bromide concentration. The present study concludes that the late Cretaceous early Tertiary oil shale deposits form the major source of the bromine species in the surface and groundwater feeding the Dead Sea. Some bromide is also contributed by the Triassic and Jurassic rocks containing evaporate salts containing bromides. Phosphate rocks of late Upper Cretaceous age contribute also with appreciable amounts of bromine species to the different water sources and hence to the Dead Sea water. At present, dissolution and erosion of bromide-rich sediments laid down by the predecessor water bodies of the present Dead Sea such as the Lisan Lake are being transported into the Dead Sea and contribute relatively large amounts of secondary bromide to the Dead Sea water.