Origin for retained activity in Pr2NiO4 while undergoing substantial phase transformation in a long-term solid oxide cell operation

Abstract

Pr2NiO4 (PNO) is a known active oxygen electrode for solid oxide cells but undergoes phase transformation at high temperatures. An in-situ synchrotron study on PNO electrodes show that phase transformation reaches nearly 100% in a long-term operation. Such significant phase transformation is expected to play a detrimental role on the cell performance. However, PNO retains the activity in an enduring operation. The origin for this dichotomy has remained obscure. The aim of this article is to investigate the origin for retained activity and performance stability in PNO electrode. High-resolution transmission electron microcopy analysis shows the presence of a large number of nanoclusters (∼ 5 nm) through the entire electrode bulk, which are localized in the 20–60 nm region. In-situ synchrotron studies show that those nanoclusters are nickelates that account for the retained activity during phase transformation.