Oriented rutile TiO2 nanorod arrays for efficient quantum dot-sensitized solar cells with extremely high open-circuit voltage

Abstract

TiO2 nanoparticles are typically employed to construct the porous films for quantum dot-sensitized solar cells (QDSCs). However, undesirable interface charge recombination at grain boundaries would hinder the efficient electron transport to the conducting substrate, giving rise to the decline of open-circuit voltage (Voc). In this work, vertically aligned architectures of oriented one-dimensional (1D) TiO2 nanorod arrays hydrothermally grown on substrates pave a way in designing highly efficient QDSCs with efficient radial-directional charge transport. SEM, TEM, XRD, and Raman spectroscopy were employed to characterize the as-prepared TiO2 nanorods, showing the rutile phase with single-crystalline structure. The homogeneous deposition of CdS/CdSe QDs on the surface of TiO2 nanorods has been achieved by in-situ grown strategies (i.e., successive ionic layer absorption and reaction, and chemical bath deposition). An extremely high Voc value up to 0.77V has been achieved for CdS/CdSe QDSCs based on the well-ordered 1D nanorod arrays. To the best of our knowledge, it is the highest Voc reported for TiO2-based QDSCs. Dependencies of photovoltaic performance, optical absorption, and interfacial charge behavior on the length of nanorods were systematically investigated. A 1.7μm nanorod-array photoelectrode-based QDSC delivers a remarkable power conversion efficiency up to 3.57% under simulated AM 1.5 100mWcm−2 illumination, attributed to the balance of competition between the increase of QD loading and suppression of interfacial recombination. This work highlights the combination of QDs with high absorption coefficient 1D architectures possessing efficient charge transport for constructing high efficiency solar cells.