Abstract
A model for describing the self-organization of chains with intra- and intermolecular interactions of the dipolar type and the birefringence (BR) effect in surface nanolayers of polymer films obtained by evaporation of a solvent is developed. Calculations of the planar orientation order parameter versus the Kuhn segment length and BR coefficient versus the film thickness are in good agreement with experimental data on investigating ordering with an inclined polarized beam for various polymer homologs.
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