Orientation dependence of the nanocrystallization and magnetic behavior during annealing of the FINEMET alloy

Abstract

The microscopic strain evolution and microstructural of FeCuNbSiB amorphous alloy samples were studied under both free and tensile stress annealing conditions using in-situ synchrotron X-ray diffraction (XRD) and transmission electron microscopy (TEM). An amorphous-nanocrystalline structure was developed in both samples after annealing at 813 K, as the microstrains increased and decreased along the parallel and perpendicular stress directions respectively. The applied stress during annealing imposed limitations on the size of nanocrystals along the tensile and perpendicular stress directions, resulting in smaller sizes compared to those obtained under free annealing conditions, due to the reduction in Gibbs free energy by the applied stress and the subsequent enhancement of nucleation rates. The nanocrystalline size perpendicular to the stress direction was slightly larger than that along the parallel stress direction because the suppression of atomic diffusion perpendicular to the stress direction during crystallization could be favorable for local atomic rearrangement.