Abstract
With 800-nm, 25-fs elliptically polarized ionization pulses, we observe molecular frame photoelectron angular distributions (MF-PADs) correlated with different dissociative ionization channels: ${\mathrm{OCS}}^{+}\ensuremath{\rightarrow}{\mathrm{S}}^{+}$+CO, ${\mathrm{CO}}^{+}$+S, ${\mathrm{CS}}^{+}$+O, and ${\mathrm{O}}^{+}$+CS. We find that the asymmetry in the MF-PAD depends on the specific dissociation channel and the laser intensities. For the dissociation channel leading to the production of ${\mathrm{O}}^{+}$, the OCS molecules are more likely to be ionized when the electric field points toward the O atom, while for other dissociation channels, they are more likely to be ionized when the electric field points toward the S atom.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.