Abstract
In this study, a method for making an orientated polymer nanocomposite film was developed. Melt-drawn nanocomposite monofilaments of isotactic polypropylene and acicular nanofillers, i.e. carbon nanotubes (CNT) or vapor grown carbon nanofibers (VGCF), were prepared and characterized from the aspect of polymer chain orientation, mechanical properties, and overall morphology. A marked improvement in mechanical properties was observed as a function of the addition of CNT, increasing draw down ratio (DDR) and annealing. Nanocomposite films were prepared from drawn monofilaments by hot-pressing under low pressure in order to maintain the orientation of the monofilaments. Wide angle X-ray diffraction showed a high degree of residual orientation in the films. Electron microscopy (high-resolution scanning electron microscopy, transmission electron microscopy) unexpectedly revealed that the CNT-matrix interface is amorphous. However, differential scanning calorimetry found no measurable influence of the CNT on the overall crystallinity as determined by the enthalpy of melting of the matrix. POLYM. COMPOS., 2013. © 2013 Society of Plastics Engineers
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