Abstract
In earlier publications from our laboratory, methods were described for the regiospecific introduction of organic substituents onto cage boron and carbon atoms in small metallacarborane clusters. Here we report the selective application of these approaches in the targeted synthesis of several double-decker, triple-decker, and tetradeckcr sandwich compounds including the parent species (C 5 Me 5 )Co(C 2 B 3 H 7 ) and (C 5 Me 5 )Co(C 2 B 3 H 5 )Co(C 5 Me 5 ).
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