Abstract
Dicyclopentadienyltitanium chloride and bromide prepared in situ from the reduction of dicyclopentadienyltitanium dichloride by isopropylmagnesium chloride and bromide, respectively, are effective dehalogenating reagents for benzylic, allylic halides and α-bromoketones. Benzylic and allylic halides are transformed into the coupling products whereas the α-bromoketones are reduced to the corresponding ketones in satisfactory yields under mild conditions.
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