Organoplatinum Complex Exhibiting Aggregation-Enhanced Emission (AEE) and Dual-Channel Ion-Sensing Properties by Terminating the Molecular Configuration Transformation (MCT) and Excited-State Intramolecular Proton Transfer (ESIPT).

Abstract

Emitters produce weak emissions when they undergo structural changes such as molecular configuration transformation (MCT) or excited-state intramolecular proton transfer (ESIPT) but give out strong emissions after terminating these distortions. Herein, an organoplatinum complex, Pt-ppy-ABP, carrying a salicylaldehyde-based Schiff base unit is synthesized. It exhibits weak emission in dilute solutions but shows bright emission at the aggregated state or after interacting with F- and Zn2+. This suggests that it has an aggregation-enhanced emission (AEE) property and holds potential in ion detection. Supported by theoretical calculations and femtosecond transient absorption results, this complex suffers excited-state structural changes including MCT from a square-planar configuration to a tetrahedral one, as well as intramolecular rotation of a monodentate ligand and ESIPT, showing weak emission in its solutions. At the aggregated state, it releases strong yellow emissions because of the restraints of MCT and ligand rotation. Upon interacting with F- or Zn2+, it emits bright-red or -green emissions, achieving detection limits of 10-7 M. The sensing mechanism is concluded as deprotonation- and coordination-induced ESIPT terminations, respectively. Given its AEE property and ion-responsive emissions, its application in information encryption is also explored. Finally, these findings should provide valuable clues for the developments of chemosensors with dual-channel recognition abilities.