Abstract
AbstractBy using organometallic reactions like Pd‐catalyzed C‐C coupling, metal‐carbon bond formation and silicon‐carbon bond cleavage, novel carbon‐rich organometallic monomers HC≡C‐C6H4‐C≡C‐[M]‐C≡C‐C6H4‐C≡CH ( [M] = ‐Ru(dppe)2‐ and (η5‐C5H4)2Fe) and organic monomers H‐(C≡C‐C6H4)X‐C≡CH (x = 1 to 3) have been obtained. They have been used for the design of novel homo and hetero metal‐containing polymers via organometallic polycondensation reactions based on quantitative metal‐carbon bond formation.
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