Abstract
The presentation focusses on integrated oxometal clusters containing fac-{M(CO)3}+ (M = Mn, Re), {Rh(η5-C5Me5)2+ or {Ru(η6-arene)}2+ organometallic subunits and oxo(alkoxo)molybdenum or tungsten subunits. The discussion adresses the following questions: i) structural relationships, ii) structural preferences, and iii) stereochemical non-rigidity. The molecular structures of the organometallic oxometal clusters are discussed in connection with those of previously reported polyoxo(alkoxo)metalates and organometallic clusters. The apparent structural relationships within these clusters underscore the electronic connection between d6-fac-{ML3} (M = Mn, Re, Ru, Rh,) and d0-fac-{MO3} or d0-fac-{MO2(OR)}+ (M = Mo, W) units.Key wordsOrganometallic oxidesoxometal clusterspolyoxometalatesmolybdenumtungstenmanganeserheniumrhodiumruthenium
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
