Abstract
A multicomponent approach of the Pn ligand complex [Cp*Fe(η5‐P5)] (1: Cp* = η5‐C5Me5) with the ditopic organic linkers 4,4′‐bipyridine (2) or trans‐1,2‐di(pyridine‐4‐yl)ethene (3) in the presence of CuI salts of the anions [BF4]– and [PF6]– or the coordinating anion Br–, leads to the formation of four novel organometallic–organic hybrid polymers: the cationic 1D polymeric compounds [Cu4{Cp*Fe(µ3,η5:1:1‐P5)}2(µ,η1:1‐C10H8N2)4(CH3CN)4]n[BF4]4n (4) and [Cu4{Cp*Fe(µ3,η5:1:1‐P5)}2(µ,η1:1‐C10H8N2)4(CH3CN)4]n[PF6]4n (5) as well as the unique neutral threefold 2D → 2D interpenetrated networks [Cu2Cl2{Cp*Fe(µ3,η5:1:1‐P5)}(µ,η1:1‐C12H10N2)]n (6) and [Cu2Br2{Cp*Fe(µ3,η5:1:1‐P5)}(µ,η1:1‐C10H8N2)]n (7).
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
