Organomagnesium Methods in Organic Synthesis

Abstract

Introduction and General References. General Considerations in the Application of Organomagnesium Compounds in Organic and Organometallic Synthesis. Preparation of Organomagnesium Compounds. Addition of Organomagnesium Compounds to Carbon-Carbon Multiple Bonds. Addition of Organomagnesium Compounds to Carbon-Nitrogen Multiple Bonds. Addition of Organomagnesium Compounds to Carbonyl Groups. Carbophilic Addition of Organomagnesium Compounds to Thiocarbonyl Groups. Substitution atCarbon by Organomagnesium Compounds. Carbenoid and Arynoid Reactions of Organomagnesium Compounds. Reactions of Organomagnesium Compounds with Proton Donors. Formation of Carbon-Nitrogen Bonds via Organomagnesium Compounds. Formation of Carbon-Oxygen Bonds via Organomagnesium Compounds. Formation of Carbon-Sulfur, Carbon-Selenium, and Carbon-Tellurium Bonds via Organomagnesium Compounds. Formation of Carbon-Halogen Bonds via Organomagnesium Compounds. Synthesis of Organoboron, Organosilicon, and Organophosphorous Compounds from Organomagnesium Compounds. Organomagnesium Compounds in the Synthesis of Other Organometallic Compounds. Index of Compounds and Methods.