Abstract
The reactions of cyanide and dimethyl sodiomalonate with 7- and 10-methyl-substituted derivatives of tricarbonyl-[1,3–6-η-4-methoxybicyclo[4.4.0]deca-3,5-dienylium]iron hexafluorophosphate have been studied. The presence of exo-methyl groups suppresses the addition of nucleophile to the angular terminus, C-1, and endo-methyl groups cause the formation of mixtures of angularly and non-angularly substituted products.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
More From: Journal of the Chemical Society, Perkin Transactions 1
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.