Abstract
cis-Triphenylgermylplatinum complexes of the type (phosphine) 2Pt(GePh 3) 2 are reported, and dipole moment measurements indicate extensive isomerisation in solution. Ligand exchange reactions with Ph 2PC 2-H 4PPh 2 and CN − either lead to new GePt complexes or result in cleavage of the PtGe bonds. Factors affecting the stability of the complexes and the mechanism of bond cleavage by H 2 and HCl are discussed. Mass spectra of the new complexes are reported.
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