Abstract

A new family of 1,2,3-triazole derivatives containing coumarin functional group with different alkyl chain lengths was synthesized and their gelation abilities and photochemistry properties were fully characterized. The main force for the self-assembly in gel state are π-π stacking and van der Waals interaction. Solubility parameters and Teas plots of the gelator and several single solvents were calculated to estimate the gelator-solvent interaction. The organogel in a binary solvent system was also characterized using various microscopic techniques including X-ray diffraction (XRD), scanning electron microscopy (SEM) and UV–vis. Reversible and stereoselective [2+2] cyclo-addition of the gel was confirmed by 1H NMR, UV absorption, fluorescence spectra and SEM. The gels formed were affected and destroyed by the addition of mercury ion.

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