Abstract
[iPr2GaN(H)tBu]2 (1) and [Mes(Cl)GaN(H)tBu]2 (2) can be synthesized by the metathesis reaction of iPr2GaCl and MesGaCl2 with one equivalent of LiN(H)tBu, respectively. 1 and 2 were characterized by NMR, IR and MS techniques as well as by X-ray structure analyses. 1 and 2 consist of centrosymmetric dimeric molecules with a Ga2N2 skeleton. According to cryoscopic measurements in benzene, both amides are dimeric in solution, too.
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