Organocalcium-Complex-Catalyzed Dehydrogenative Silylation and Mono/Dihydrosilylation Tandem Reactions of Terminal Alkynes.

Abstract

In principle, catalytic dehydrogenative silylation and mono/dihydrosilylation tandem reactions of terminal alkynes with hydrosilanes provide gem-disilylated alkenes or gem-trisilylated alkanes, but very little progress has been made. Herein, we report organocalcium-complex-catalyzed dehydrogenative silylation and mono/dihydrosilylation tandem reactions of terminal alkynes with hydrosilanes in one pot, which produce gem-disilylated alkenes in moderate yields and gem-trisilylated alkanes in high yields. We also briefly demonstrate that the synthesized gem-disilylated alkenes can be easily transformed into other organosilanes.