Abstract
Abstract[[CpNi(dRpf)]+ (dRpf=1,1’‐bis(di‐R‐phosphino)ferrocene, R=phenyl (dppf) [1]+, iso‐propyl (dippf) [2]+, and cyclohexyl (dcpf) [3]+), CpNi(dRpf)]+(dRpf=1,1’‐bis(di‐R‐phosphino)ferrocene, R=phenyl (dppf) [1]+, iso‐propyl (dippf) [2]+, and cyclohexyl (dcpf) [3]+), showed two reversible electrochemical processes, one cathodic and one anodic in the cyclic voltammogram. CpNiI was generated in the cathodic processes for all three complexes, while spectroscopic data and dft analysis for the anodic process suggested contributions from the ferrocene, there was some degree of delocalization onto the Ni ion.
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