Abstract
Abstract[[CpNi(dRpf)]+ (dRpf=1,1’‐bis(di‐R‐phosphino)ferrocene, R=phenyl (dppf) [1]+, iso‐propyl (dippf) [2]+, and cyclohexyl (dcpf) [3]+), CpNi(dRpf)]+(dRpf=1,1’‐bis(di‐R‐phosphino)ferrocene, R=phenyl (dppf) [1]+, iso‐propyl (dippf) [2]+, and cyclohexyl (dcpf) [3]+), showed two reversible electrochemical processes, one cathodic and one anodic in the cyclic voltammogram. CpNiI was generated in the cathodic processes for all three complexes, while spectroscopic data and dft analysis for the anodic process suggested contributions from the ferrocene, there was some degree of delocalization onto the Ni ion.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
