Abstract
Abstract The salts of arylsulfinic acids were found to react with alkyl chlorosulfite to form alkyl sulfinates. p-Toluenesulfinic acids-18O was synthesized and treated with ethyl chlorosulfite to give ethyl p-toluenesulfinate-18O, which retained half of the oxygen atoms existing in the original sulfinic acid. A mechanism for this novel reaction was proposed.
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