Organic Pollutants and Chemicals of Emerging Concern at the atmospheric background stations of the German Environment Agency Air Monitoring Network

Abstract

Within the framework of multiple international conventions, Germany like other state parties is committed to monitor the air quality in the atmospheric background. Therefore, atmospheric measurements are realized by the German Environment Agency (Umweltbundesamt - UBA) with its network of 7 remote measurement stations throughout the rural background of Germany. These stations are operated by personnel and contribute data on pollutant deposition and transboundary long-range transport to the following monitoring programs: Global Atmosphere Watch (GAW), European Monitoring and Evaluation Program (EMEP), Convention on the Protection of the Marine Environment of the Baltic Sea Area (HELCOM), Convention for the Protection of the Marine Environment of the North-East Atlantic (OSPAR) and as well as to the EU commission within the directive on ambient air quality and cleaner air for Europe (2008/50/EC). Some pollutants are measured continuously since the late 1960s, while other pollutants especially metals and semi-metals are monitored since the early 1990s. Organic pollutants such as PAHs and POPs are regularly monitored as well starting in the mid-1990s in precipitation and since the mid-2000s also in air and the aerosol phase. Therefore, the UBA air monitoring network contributes to the supervision of the Stockholm convention and the respective EU Regulation (2019/1021) on persistent organic pollutants. Recently further chemicals of emerging concern were included to the list of substances that are measured at the UBA air monitoring stations. Within a three-year project period, fluorinated organics such as per- and polyfluorinated substances (PFAS) and a range of current used pesticides (CUP) will be measured for the next two years in precipitation and air. This work presents the history of PAH and POP measurements at the UBA air monitoring network and the novel compounds of interest with the applied techniques for their detection and monitoring over the coming years.