Organic matter deposition and paleoenvironmental implications across the Cenomanian-Turonian boundary of the Subalpine Basin (SE France): Local and global controls

Abstract

The Cenomanian-Turonian boundary is marked by global sea-level highstands and one of the warmest periods of the Mesozoic, with high pCO2 levels linked to a massive magmatic episode. This is associated with the establishment of a worldwide marine anoxia, the deposition of organic-rich facies and disturbances of the global carbon cycle, the so-called Oceanic Anoxic Event 2 (OAE2). The Pont d'Issole section's (Subalpine Basin, SE France) sedimentary succession represents the reference record of OAE2 in the Tethyan domain, although its organic fraction is extremely poorly studied. Therefore, the main objectives of this study are the characterization of the Pont d'Issole section's organic matter (OM) for paleoenvironmental interpretation and the assessment of the OM thermal maturity using organic petrology and organic geochemistry techniques.The organic record characterizes a shallowing-up marine system with varying redox and restriction conditions, associated with periods of stratified oxygen regimen. It displays the presence of two OM enrichment episodes with different paleoenvironmental and geodynamic contexts. The first OM enrichment episode (Unit Th1) is thought to be associated with the global mechanisms that trigger OAE2 and is characterized by a palynofacies association co-dominated by amorphous OM and marine microplankton, reflecting a context of high sea-level. This is followed by the Plenus Cold Event (Unit Th2), characterized by a decrease in amorphous OM and increase in marine microplankton, representing a reoxygenation associated with an increase in water level, and an apparent decrease in temperature (disappearance of Classopollis sp.). The second OM enrichment episode (Unit Th3 and base of Unit Th4) is characterized by an association dominated by amorphous OM, the occurrence of freshwater microplankton, and the development of a restricted environment with low sea level. These depositional conditions are thought to be connected to the beginning phases of basin closure, promoted by the regional tectonic framework (compressive trend between Africa and Europe).The molecular fraction showed the presence of unsaturated compounds, monoaromatic steranes, monoaromatic anthrasteroids and the biological ββ hopanes, indicating a low thermal evolution for the OM. This is corroborated by biomarkers ratios and organic petrographic data, namely vitrinite reflectance (0.29% Rr).The presence of Paleozoic reworked OM in the samples was also identified presenting a more complex thermal history than the Cretaceous OM. This OM is possibly related to the subaerial erosion of Hercynian Massifs.