Organic Amine-Bridged Quasi-2D Perovskite/PbS Colloidal Quantum Dots Composites for High-Gain Near-Infrared Photodetectors.

Abstract

Near-infrared (NIR) II detection at weak flux intensity is required in medical imaging and is especially urgent in light of the low quantum efficiency of NIR-II dyes. The low responsivity of traditional photodetectors in this region limits image quality. Here, we report a NIR-II photodetector with high gain based on perovskite coupled PbS colloidal quantum dots (CQDs). Tailoring the trap density of CQDs by designing surface ligands with dual functionality contributed to control over trap-induced charge-injection upon light illumination. As a result, a detector with high gain is realized, showing external quantum efficiency of 1260% at 1200 nm and achieving the lowest detectable light intensity, that is, as low as 0.67 pW cm-2 with a linear dynamic range of 200 dB. Devices maintain over 90% of responsivity after 150 days of storage. We acquired images of a butterfly wing, showing the skeleton texture with a maximum spatial resolution of 3.9 lp/mm.