Abstract

The partial structure factors, S ij(q), and thermodynamic properties of a model liquid binary alloy are calculated in the mean spherical approximation. It is assumed the ordering potential, v(r) = 1 2 [ϕ 11( r) + ϕ 22( r) − 2ϕ 12( r)] , is given by a screened Coulomb potential form, and is dependent on concentration. The functional behaviour of v(r) is chosen so that it describes phase separating tendencies at one concentration range, and compound forming tendencies at another. This type of behaviour appears to be present in liquid NaCd.

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