Abstract
Long-range ordering emerges in poly(3-hexylthiophene) (P3HT) solutions during time-dependent aggregation. Here, aggregation of P3HT in chloroform solution was induced by ultrasonication, aging, and combinations thereof. UV–vis spectroscopy and polarized optical microscopy demonstrated that long-range ordering in the solution and subsequently the solid state depends on assembled P3HT fiber length, as determined by film atomic force microscopy. Ultrasonication induced the formation of fibers that were relatively short compared to those obtained through aging. As a result, ultrasonication afforded isotropic solutions and films, whereas aging afforded anisotropic solutions and films. The impact of fiber length and anisotropy on macroscopic charge transport performance was evaluated using an organic field-effect transistor (OFET) architecture. Both aged and sonicated solutions exhibited charge carrier mobilities that were an order of magnitude higher than that obtained for pristine samples. Aging of sonicated ...
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