Ordered Mesopore Confined Pt Nanoclusters Enable Unusual Self-Enhancing Catalysis.

Abstract

As an important kind of emerging heterogeneous catalyst for sustainable chemical processes, supported metal cluster (SMC) catalysts have received great attention for their outstanding activity; however, the easy aggregation of metal clusters due to their migration along the substrate's surface usually deteriorates their activity and even causes catalyst failure during cycling. Herein, stable Pt nanoclusters (NCs, ∼1.06 nm) are homogeneously confined in the uniform spherical mesopores of mesoporous titania (mpTiO2) by the interaction between Pt NCs and metal oxide pore walls made of polycrystalline anatase TiO2. The obtained Pt-mpTiO2 exhibits excellent stability with well-retained CO conversion (∼95.0%) and Pt NCs (∼1.20 nm) in the long term water-gas shift (WGS) reaction. More importantly, the Pt-mpTiO2 displays an unusual increasing activity during the cyclic catalyzing WGS reaction, which was found to stem from the in situ generation of interfacial active sites (Ti3+-Ov-Ptδ+) by the reduction effect of spillover hydrogen generated at the stably supported Pt NCs. The Pt-mpTiO2 catalysts also show superior performance toward the selective hydrogenation of furfural to 2-methylfuran. This work discloses an efficient and robust Pt-mpTiO2 catalyst and systematically elucidates the mechanism underlying its unique catalytic activity, which helps to design stable SMC catalysts with self-enhancing interfacial activity in sustainable heterogeneous catalysis.