Order-disorder transition in one-dimensional system with disorder in composition

Abstract

The influence of structural inhomogeneity onto order-disorder transitions in 1D systems is considered in the scope of the Potts-like model with many-particle interactions. The helix-coil transition in DNAs, heterogeneous by hydrogen bonding energy, is considered as an example. The microcanonical method is employed to evaluate the free energy. The secular equation for the heteropolymer is constructed. Both the melting temperature and interval of DNA melting are obtained. In the limit of small difference between inverse melting temperatures of poly(A-T) and poly(G-C), the coincidence with classical results is obtained.