Abstract
A π–d hybrid electronic system, (DMe-DCNQI)2Cu, where the π orbital of the organic molecule, DMe-DCNQI, is strongly hybridized with the d xy orbital of Cu, has been studied by 15 N and 13 C NMR at three sites. The analysis of Knight shift, K, and local spin susceptibilities in the π and d orbitals was carried out separately. The π and d spin susceptibilities were found to be quite different in magnitude and temperature dependence. Moreover, the Knight shift was separated into those of two constituent bands; a one-dimensional π band and a three-dimensional π–d band. The relative weight of the band susceptibilities is strongly temperature dependent.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
