Abstract
Changes in the structure of different drawn polyethylene (PE) fibres are studied by the Becke' line method and interferometrically. The Becke' line method is used to study the changes in the optical properties of the skin layer of PE undrawn fibres. A Pluta polarizing interference microscope is used to determine the mean refractive indices and mean birefringence of the drawn fibres. Some structural parameters, such as optical orientation function, electric polarizability difference and isotropic polarizability (Δα/3α0), are determined. This last parameter is found to be constant and depends only on the fibre structure. The number of molecules per unit volume and the distribution of segments at an angle with respect to the draw ratio are also determined. The generalized Lorentz–Lorenz equation given by de Vries is used to determine PE fibre structural parameters. A comparison between the experimental and those obtained using the Lorentz–Lorenz equation is given. A refractive index profile can assist fibre characterization. An empirical formula is suggested to correlate the changes in A, Δn, fθ and θ with the draw ratio, and its constants are determined. Microinterferograms and curves are given for illustration. © 1999 Society of Chemical Industry
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