Abstract
Preactivation can play a promising role in suppressing oxygen loss during the first charging process in Li-rich oxide cathode materials, relieving a series of problems such as large initial irreversible capacity loss, structure transformation due to ion rearrangement, and oxidation/decomposition of the electrolyte. However, the strategies previous adopted are mainly chemical delithiation, which has violent effect on the crystal structure and deteriorates the cycle performance. Here, we report a facile and effective microwave-assisted treatment method to preactivate Li-rich layered oxides without structural distortion. The microwave-treated sample shows a high discharge capacity of about 281 mAh g–1 with a Coulombic efficiency of 87% at 0.1 C and exhibits unnormal continuous increase of discharge capacity from 203 mAh g–1 to 218 mAh g–1 during 110 cycles at 1 C as well as presents distinctly improved cycling stability. EIS, GITT and XRD studies reveal that the kinetics of electrochemical reaction on electr...
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