Optimizing the Preparation Process of Refined Asphalt Based on the Response Surface and Preparation of Needle Coke.

Abstract

Refined asphalt was prepared by solvent extraction sedimentation based on the response surface design, using washing oil and kerosene as solvents and the coal tar pitch as raw materials. The mathematical models of the refined asphalt yield, quinoline insoluble (QI) content, ash content, solvent-to-oil ratio, aromatic-to-aliphatic hydrocarbon ratio, extraction temperature, and sedimentation time were proposed, analyzing the influence of each factor and their interactions on the response values. Therefore, the optimal combination of preparation process parameters and better operation window was obtained by optimizing the experiment. Meanwhile, refined asphalt with high QI content and low QI content was selected as raw material, and the needle coke was prepared through the process of carbonization and calcination. The influence of QI content on the composition and the structure of green coke and needle coke was investigated by X-ray diffraction (XRD), Raman spectra, and polarizing microscopy characterizations. The results showed that the solvent-to-oil ratio is 1.2, aromatic-to-aliphatic hydrocarbon ratio is 1.1, sedimentation time is 2 h, and extraction temperature is 110 °C, resulting in the yield of refined asphalt being 76%, QI content being less than 0.1%, and ash content being less than 0.05%, which meets the requirement of the high-quality needle coke. Otherwise, refined asphalt with lower QI content easily generates a mesophase with more fibers and a large structure in the thermal conversion process, and the corresponding green coke and needle coke have a relatively regular carbon microcrystalline structure.