Optimizing the performance of a graphite anode for innovative metal-ion batteries and hybrid capacitors

Abstract

Herein, we present an optimum method for maximizing the electrochemical performance of graphite anodes using two heat treatment methods involving graphite intercalated compound (GIC) group within graphite, namely, thermal shock (TS; directly input target temperature) and gradual heating (GH; including ramping time). Different heating methods for preparing expanded graphite (EG) involve different reactions, relaxation times, and diffusion pathways for the diffusion of metal ions into EG. We find that rapidly shocking the layered structure can facilitate faster lithium and potassium ion diffusion from EG (TS) (heated for 30 min) via different intercalation/deintercalation processes compared to that from EG (GH). Consequently, EG (TS) exhibits the most significantly improved electrochemical performance among the lithium and potassium ion half-cells. For full lithium-ion hybrid capacitors (LIHCs), EG (TS)||activated carbon (AC) shows reasonable values of maximum power density (2.8 kW kg−1 with 59.12 Wh kg−1) and energy density (196.41 Wh kg−1), demonstrating its ultrahigh durability (capacity retention: 70.01%) over 12000 cycles at 2.0 A g−1. In addition, for potassium-ion hybrid capacitors (PIHCs), reasonable performance is achieved (average capacity of 82.02 mAh g−1 at 1.0 A g−1 over 2000 cycles with 94.35% capacity retention), demonstrating the high efficiency of PIHCs for substituting LIHCs without any systematic alterations.