Abstract
Developing sustainable and low-cost bio-reduction technologies is essential for vanadium (V) bioremediation in groundwater. With both agricultural waste (wheat stalk) being a solid carbon source and ceramsite and medical stone being auxiliary packings, V(V) removal was confirmed and optimized in this study. The ratio of ceramsite to medical stone was maintained at 1:3 in Group I, which accomplished a V(V) removal efficiency up to 97.5% within 120 h and an average removal rate was around 0.305 mg/(L·h). The dissolution and utilization of carbon and trace elements (Mg, Fe, Mo and Ni) by microbes also contributed to the V(V) bio-reduction enhancement. The main components of DOM (tryptophan and humic acid-like substances) were vital in the V(V) binding and electron transfer processes. This study could promote the current knowledge on the sustainable V(V) bioremediation by using agricultural waste and auxiliary packings.
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