Optimizing surfactant templating of yttria-stabilized zirconia aerogels for high-temperature applications: Effect of cationic surfactant

Abstract

Aerogels can be used in spaceflight applications as thermal insulators due to their low density, low thermal conductivity, and tortuous path for solid conduction. However, the aerogel formulation must be optimized to increase the thermal stability of the aerogels, as a drastic densification and decrease in surface area often is exhibited after high-temperature exposure. This work considers yttria-stabilized zirconia (YSZ) aerogels, which have low thermal conductivity and are expected to be used for temperatures between 600 °C and 1000 °C. It is anticipated that new sol-gel chemistries will yield YSZ aerogels that exhibit retained mesoporous structure, increased surface area, and minimized shrinkage upon exposure to higher temperatures in the expected use range. This work investigates the addition of surfactant to 20 mol% YSZ aerogels. The cationic surfactant, cetrimonium bromide (CTAB), was used as the templating agent, preventing the collapse of the mesoporous structure upon gelation and drying. It was determined that adding one-half times the critical micelle concentration of CTAB increased the surface area of the aerogels by 72% and 41% and increased the pore volume following exposure to 600 °C and 1000 °C, respectively. This level of CTAB had the greatest increase in surface area and pore volume as compared to aerogels without CTAB or with twice the critical micelle concentration of CTAB. By optimizing the concentration of CTAB, the thermal stability of YSZ aerogels can be enhanced to make these materials more efficient when used as thermal management systems. • Thermally stable aerogels can be used in high-temperature applications. • Surfactant templating can influence the mesoporous structure of aerogels. • Cetrimonium bromide (CTAB) can be used as an effective surfactant template. • Lower amounts of CTAB promote high surface area and pore volume at high temperature. • Aerogels with high surface area and pore volume are efficient thermal insulators.