Optimizing degradation conditions of treatment of TATB explosive wastewater by γ-Fe2O3 nanoparticles and UV synergistic degradation

Abstract

In this work, the effect of superparamagnetic γ-Fe2O3 nanoparticles and ultraviolet light (UV) synergistic degradation on the treatment of 1,3,5-triamino-2,4,6-trinitrobenzene (TATB) explosive wastewater was studied. γ-Fe2O3 nanoparticles were prepared by hydrolysis method and the degradation performance of TATB explosive wastewater was systematically studied with UV light assisted. The results showed that γ-Fe2O3 magnetic nanoparticles have a low size distribution that ranged from 5 to 10 nm and possesses superparamagnetic properties. The optimized degradation condition was investigated and best degradation performance was obtained with the optimized conditions: the initial of pH = 3, UV illumination intensity (5 w/cm2), reaction temperature (25 °C), initial total organic carbon concentration (4.025 mg/L) as well as reaction time (60 min). This work can offer a new idea to degrade the explosive wastewater.