Optimized microwave absorption properties of FeCoCrAlGdx high-entropy alloys by inhibiting nanograin coarsening

Abstract

High-entropy alloys (HEAs) with nanoscale crystal structure have supposed to be good microwave absorbers due to their excellent soft magnetic properties. Annealing is typically employed to optimize microwave absorption, however, grain coarsening motivated by temperature will lead to serious deterioration of soft magnetic properties. Herein, we introduce the rare earth (RE) element Gd into FeCoCrAlGdx (x = 0, 0.1, 0.2, 0.3) HEAs, which is expecting to inhibit the nanograin coarsening through dispersing Gd2O3. The incorporation of Gd results in a low coercivity (Hc), high saturation magnetization (Ms), and high complex permeability (μ′ and μ″) of the HEAs. Especially, the Hc for as-annealed FeCoCrAlGd0.2 (114 Oe) is only 60.6 % of that for as-annealed FeCoCrAl (188 Oe). Owing to the remarkable magnetic properties, all Gd-doped HEAs have a larger effective absorption bandwidth at lower thicknesses. The reflection loss (RL) of as-annealed FeCoCrAlGd0.1 reaches a maximum absorption of −45 dB and an effective absorption bandwidth of 5 GHz (thickness is 1.5 mm). In addition, DFT (density functional theory) calculations are performed to analyze the energies and magnetic moments of the systems. This article provides guidance for design of high performance soft magnetic microwave absorbers.