Abstract

Al-doped ZnO (AZO)/Ag/AZO multilayer coatings (50–70nm thick) were grown at room temperature on glass substrates with different silver layer thickness, from 3 to 19nm, by using radio frequency magnetron sputtering. Thermal stability of the compositional, optical and electrical properties of the AZO/Ag/AZO structures were investigated up to 400°C and as a function of Ag film thickness. An AZO film as thin as 20nm is an excellent barrier to Ag diffusion. The inclusion of 9.5nm thin silver layer within the transparent conductive oxide (TCO) material leads to a maximum enhancement of the electro-optical characteristics. The excellent measured properties of low resistance, high transmittance in the visible spectral range and thermal stability allow these ultra-thin AZO/Ag/AZO structures to compete with the 1μm thick TCO layer currently used in thin film solar cells.

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