Abstract
Application of biochar-based fertilizers is increasingly being considered for its potential agronomic and environmental benefits. However, biochar may contain residues of polycyclic aromatic hydrocarbons (PAHs) as a result of its production by pyrolysis. The strong adsorption of PAHs to biochar makes extraction and analysis of biochar-based fertilizers difficult. This study optimizes the extraction of PAHs in biochar-based fertilizer samples by using an ultrasonic bath for quantification by gas chromatography-mass spectrometry. Among 12 solvents, acetone-cyclohexane (1:1) mixture was selected as the optimum solvent for extraction. Three variables affecting the extraction were studied by Box-Behnken design. The optimum conditions were 57°C extraction temperature, 81min extraction time, and two extraction cycles, which were validated by assessing the linearity of analysis, LOD, LOQ, recovery, and levels of PAHs in real biochar-based fertilizer samples. Results revealed that the 16 U.S. EPA PAHs had good linearity, with squared correlation coefficients greater than 0.99. LODs were low, ranging from 2.2ngg(-1) (acenaphthene) to 23.55ngg(-1) (indeno[1,2,3-cd]perylene), and LOQs varied from 7.51ngg(-1) to 78.49ngg(-1). The recoveries of 16 individual PAHs from the three biochar-based fertilizer samples were 81.8-109.4%. Graphical Abstract Use of RSM to optimize UAE for extraction of the PAHs in biochar-based fertilizer.
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