Optimization of reduced Graphene oxide synthesis using central composite design analysis-A waste to value approach.

Abstract

In recent times, reduced graphene oxide has gained more attention in various fields. In our study, a direct synthesis of reduced graphene oxide using a novel carbon-rich agro-waste from Pennisetum glaucum was used. Ferrocene acted as an oxidizing agent during thermal degradation at 300°C for 15 and 20min to promote graphene oxide and reduced graphene oxide formation. The X-ray diffraction peak at 2θ indicating a shift from 16.86 to 24.28°, presence of functional groups like -OH stretching, -C = C-, C = O, C-O, and C-OH by Fourier transmission infrared spectroscopy, prominent D and G bands at 1308cm-1 and 1578cm-1 by Raman spectra and UV-visible spectroscopy peak shift from 235 to 245nm (π-π*, C = C bonds) confirmed the reduction of graphene oxide to reduced graphene oxide. The average particle size values 233.3nm for graphene oxide and 63.57nm for reduced graphene oxide illustrate the nanoscale range of our synthesized material. The negative zeta potential values in the range - 45.5mV and - 29.5mV for graphene oxide and its reduced forms infer the dispersion stability along with surface oxygen group presence. We have also highlighted the formation of graphene oxide quantum dots by magnetic stirring and confirmed by UV transilluminator and photoluminescence spectra. The photodegradation efficiency was optimized using central composite design for dosage, dye concentration, pH, and time for both malachite green and reactive blue dye. The kinetic studies report pseudo-first-order kinetic model for catalytic degradation and statistical Analysis of variance proved the significance of the process for p value < 0.05. Thus, the synthesized graphene materials could be used as a potential candidate for environmental applications.